18661-69-3Relevant academic research and scientific papers
Kinetics and Mechanism of Autocatalytic Oxidation of Fe(phen)32+ and Fe(bpy)32+ by Nitric Acid
Lengyel, Istvan,Barna, Terez,Bazsa, Gyoergy
, p. 229 - 236 (2007/10/02)
The kinetics of the title reactions has been studied and the investigation of the oxidation of the iron(II) aqua ion by nitric acid has been extended.All three reactions are autocatalytic in nature.Oxidation of Fe(aq)2+ is practically complete
Electron transfer between neptunium(VI) and substituted 1,10-phenanthroline and 2,2′-bipyridine complexes of iron(II)
Pelizzetti,Woods,Sullivan
, p. 3973 - 3974 (2008/10/08)
The kinetics of electron transfer between Np(VI) and some complexes of iron(II) with phenanthroline-like ligands have been investigated by means of a stopped-flow spectrophotometric technique. The rate constants and the related activation parameters have been discussed in the light of the Marcus theory for outer-sphere electron transfers.
