187411-17-2Relevant academic research and scientific papers
Synthesis and characterization of (4-fluorophenyl)amino-based amino- and iminometallanes of group 13. Crystal structures of (MeAlNRf)4, (MeMNRf)6·nTHF (M = Al, n = 2; M = Ga, n = 7), and (MeIn(THF)NRf)4 (Rf = 4-C6H4F)
Schnitter, Christoph,Waezsada, Said D.,Roesky, Herbert W.,Teichert, Markus,Uso?n, Lsabel,Parisini, Emilio
, p. 1197 - 1202 (1997)
The novel amino- and iminometallanes (MeAlNRf)n (1) (n = 4, la; n = 6, 1b), (Me2GaN-(H)Rf)2 (2), (Me2GaNRf)6 (3), (Me2InN(H)Rf)2 (4), and (MeIn(THF)NRf)4 (5) (Rf = 4-C6H4F) have been prepared in high yield by the reaction of AlMe3, GaMe3, and InMe3, respectively, with 4-fluoroaniline. All of the products have been fully characterized by elemental analysis, IR, NMR, and mass spectroscopy. The crystal structures of 1a, 1b·2THF, 3·7THF, and 5 have been determined. For the degree of oligomerization of compound 1 a solvent- and temperature-dependent influence is assumed. (MeGaNRf)4 (3) is the first hexameric iminogallane and (MeIn(THF)NRf)4 (5) is the second iminoindane described in the literature.
