187975-06-0Relevant academic research and scientific papers
NHC-Stabilized Radicals in the Formal Hydroacylation Reaction of Alkynes
Phan, Jenny,Ruser, Stephanie-M.,Zeitler, Kirsten,Rehbein, Julia
, p. 557 - 561 (2019)
Mechanistic details of transformations catalyzed by N-heterocyclic carbenes (NHC) are currently of great interest, targeting questions on the active catalyst in operation and the structure and reactivity of key intermediates. These mechanistic studies are
Structures and reactivities of O-methylated Breslow intermediates
Maji, Biplab,Mayr, Herbert
supporting information, p. 10408 - 10412 (2012/11/07)
As close as you can get: Since Breslow intermediates usually exist in their keto form, their O-protected tautomers may be considered as their closest isolable relatives. A series of these compounds have been synthesized, their structures determined, and the kinetics of their reactions with electrophiles investigated. Copyright
Kinetics of C(2α)-proton abstraction from 2-benzylthiazolium salts leading to enamines relevant to catalysis by thiamin-dependent enzymes
Barletta, Gabriel L.,Zou, Yu,Huskey, W. Phillip,Jordan, Frank
, p. 2356 - 2362 (2007/10/03)
The kinetics of proton transfer from the C(2α) position of 2-(1-methoxybenzyl)thiazolium salts was studied for the p-H and p-N(CH3)3+ derivatives as models for the protonation of the enamine/C(2α)-carbanion, a key intermed
