18805-23-7

Upstream product

• 60-29-7 diethyl ether 
• 701-73-5 methyl N-phenyldithiocarbamate 
• 74-88-4 methyl iodide 
• 103-72-0 phenyl isothiocyanate 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 
• 75-15-0 carbon disulfide 
• 62-53-3 aniline 

Downstream Products

• 54985-77-2 C₁₆H₁₇NOS₂ 
• 40279-09-2 2-methylmercapto-1-phenylimidazole 
• 86601-30-1 (5,6-Dimethyl-1H-benzoimidazol-2-yl)-phenyl-amine 
• 21578-58-5 (1H-benzoimidazol-2-yl)phenylamine 
• 86601-34-5 (5-nitro-1⁽³⁾H-benzimidazol-2-yl)-phenyl-amine 
• 97934-60-6 N-phenyl-N-phenoxyacetyldithiocarbamic methyl ester 
• 137628-92-3 3-Methoxy-3-methyl-4,4-bis(methylthio)-1-phenyl-2-azetidinone 
• 1848-75-5 N-phenyl-N-(4,5-dihydro-1H-imidazol-2-yl)amine 
• 343774-56-1 5,5-Dimethyl-2-phenylimino-1,3-oxathiolan 
• 343219-99-8 2'-(Phenylimino)spiro 
• 76718-18-8 5-(3-Cyclohexenyl)-2-phenylimino-1,3-oxathiolan 
• 137629-01-7 3-Methoxy-3-methyl-1-phenylazetidine-2,4-dione 
• 5416-30-8 N,N'-diphenyl-S-methyl isothiourea 
• 86601-38-9 (5-chloro-1⁽³⁾H-benzoimidazol-2-yl)-phenyl-amine 

Relevant academic research and scientific papers

Microwave-assisted from synthesis of 2-arylamino-2-imidazolines on a solid support

An efficient synthesis of 2-arylamino-2-imidazolines from dimethyl N-aryldithioimidocarbonates and ethylenediamine on solid support under microwave irradiation has been developed. The reaction time has been reduced from hours to minutes with improved yiel

Triphosgene: A versatile reagent for the synthesis of azetidin-2-ones

An efficient use of triphosgene, as an acid activator, for the synthesis of substituted azetidin-2-ones via ketene-imine cycloaddition reaction using various acids and imines have been described.

The efficient synthesis of 2-arylamino-2-imidazolines, 2-heteroaryl- substituted benzimidazoles, and their morpholin-4-ylmethyl derivatives

2-Heteroaryl-substituted 1H-benzimidazoles were synthesized in good yields by heating the HSO3 adducts of heteroaromatic aldehydes with o-phenylenediamine in DMF under reflux. This procedure is more general and shorter than earlier methods. 2-Arylamino-2-imidazolines were prepared by heating dimethyl aryldithioimidocarbonates and ethylenediamine under reflux. The imine-enamine tautomerization of 2-arylamino-2-imidazolines was investigated by means of 1H-NMR spectroscopy. Morpholin-4-ylmethyl derivatives of the benzimidazole and imidazoline products were synthesized regioselectively by treatment with morpholine and formaldehyde.

Difluoromethylation of Methyl Aryldithiocarbamates

Reactions of methyl aryldithiocarbamates with chlorodifluoromethane in 10% NaOH in the presence of tetrabutylammonium hydrogen sulfate at 0-30°C give methyl difluoromethyl arylimidodithiocarbonates and, in low yields, methyl N-aryl-N-difluoromethyldithioc