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188357-34-8

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188357-34-8 Usage

Description

Ethyl2,3-di-O-benzyl-4,6-O-benzylidene-a-D-thiomannopyranosideS-oxide is a complex organic compound with a unique chemical structure. It is a white solid that is characterized by its benzyl and benzylidene groups, which contribute to its chemical properties and potential applications.

Uses

Used in the Direct Synthesis of β-Mannopyranosides:
Ethyl2,3-di-O-benzyl-4,6-O-benzylidene-a-D-thiomannopyranosideS-oxide is used as a key intermediate in the direct synthesis of β-mannopyranosides by the sulfoxide method. This method is a valuable approach in the field of carbohydrate chemistry, as it allows for the efficient and selective synthesis of β-mannopyranosides, which are important structural components in various biological systems.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, Ethyl2,3-di-O-benzyl-4,6-O-benzylidene-a-D-thiomannopyranosideS-oxide can be used as a building block for the development of novel drugs targeting various diseases. Its unique chemical structure and reactivity make it a promising candidate for the synthesis of complex carbohydrate-based therapeutics.
Used in Chemical Research:
Ethyl2,3-di-O-benzyl-4,6-O-benzylidene-a-D-thiomannopyranosideS-oxide is also used in chemical research, particularly in the study of carbohydrate chemistry and the development of new synthetic methods. Its unique structure and properties make it an interesting subject for researchers to explore and potentially discover new applications and reactions.
Used in Material Science:
In the field of material science, Ethyl2,3-di-O-benzyl-4,6-O-benzylidene-a-D-thiomannopyranosideS-oxide may find applications in the development of new materials with specific properties, such as improved biocompatibility or enhanced chemical stability. Its unique structure and reactivity could contribute to the creation of novel materials with potential applications in various industries.

Check Digit Verification of cas no

The CAS Registry Mumber 188357-34-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,8,3,5 and 7 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 188357-34:
(8*1)+(7*8)+(6*8)+(5*3)+(4*5)+(3*7)+(2*3)+(1*4)=178
178 % 10 = 8
So 188357-34-8 is a valid CAS Registry Number.
InChI:InChI=1/C29H32O6S/c1-2-36(30)29-27(32-19-22-14-8-4-9-15-22)26(31-18-21-12-6-3-7-13-21)25-24(34-29)20-33-28(35-25)23-16-10-5-11-17-23/h3-17,24-29H,2,18-20H2,1H3/t24?,25-,26+,27-,28?,29-,36?/m1/s1

188357-34-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethyl2,3-di-O-benzyl-4,6-O-benzylidene-a-D-thiomannopyranosideS-oxide

1.2 Other means of identification

Product number -
Other names 1-Deoxy-1-(ethylsulfinyl)-2,3-bis-O-(phenylMethyl)-4,6-O-[(R)-phenylMethylene]

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:188357-34-8 SDS

188357-34-8Downstream Products

188357-34-8Relevant articles and documents

Synthesis of 12- O-Mono- and Diglycosyl-oxystearates, a New Class of Agonists for the C-type Lectin Receptor Mincle

Van Huy, Le,Tanaka, Chiaki,Imai, Takashi,Yamasaki, Sho,Miyamoto, Tomofumi

supporting information, p. 44 - 49 (2019/01/15)

Fifteen glycosyl-oxystearates were synthesized by Crich's 4,6-benzylidene and K?ening-Knorr strategies. Assessment of structure-activity relationships using macrophage-inducible C-type lectin (Mincle) receptor cells expressing nuclear factor of activated

Direct chemical synthesis of β-mannopyranosides and other glycosides via glycosyl triflates

Crich, David,Sun, Sanxing

, p. 8321 - 8348 (2007/10/03)

High yield, highly stereoselective methods for the synthesis of β- mannopyranosides primary, secondary, and tertiary alcohols are presented. Activation of mannosyl sulfoxides or mannosyl thioglycosides with trifluoromethanesulfonic anhydride or benzenesulfenyl triflate, respectively, leads to the efficient formation of α-mannosyl triflates at -78 °C in dichloromethane, in the presence of 2,6-di-tertbutyl-4-methylpyridine. These triflates then react S(N)2-like with alcohols to give the β-mannosides. The use of a 4,6-O-benzylidene protected mannose is required for high selectivity, as is the use of non-participating protecting groups on O-2 and O-3 of the donors. It is further demonstrated that the thioglycoside/benzensulfenyl triflate activation is applicable in the glucoside series, when both armed and disarmed protecting groups are tolerated.

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