188430-17-3Relevant articles and documents
"Syn-Effect" in the Desulfonylation Reaction of α,α-Dialkylated (E)-Allylic Sulfones
Shibayama, Atsushi,Nakamura, Tetsuya,Asada, Takahiro,Shintani, Takehiko,Ukaji, Yutaka,Kinoshita, Hideki,Inomata, Katsuhiko
, p. 381 - 396 (2007/10/03)
It was found that the desulfonylation reaction of α,α-dialkylated (E)-allylic sulfones with a base preferentially affords the sterically unfavorable (Z)-alkadienes. The relative degree of the "syn-effect", which is herein defined as an effect which stabil