188444-03-3

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 188443-91-6 (S)-2-(4-Methoxy-benzylsulfanyl)-3-(2-methoxy-ethoxymethoxy)-2-methyl-propionic acid ethyl ester 
• 188443-92-7 (S)-2-(4-Methoxy-benzylsulfanyl)-3-(2-methoxy-ethoxymethoxy)-2-methyl-propionic acid 
• 114191-22-9 Ethyl (2S,3E)-2-(4-methoxybenzylthio)-2-methylpent-3-enoate 
• 123401-95-6 Ethyl (2S)-2-formyl-2-(4-methoxybenzylthio)propanoate 
• 554-12-1 propanoic acid methyl ester 
• 188443-99-4 (S)-1-Imidazol-1-yl-2-(4-methoxy-benzylsulfanyl)-3-(2-methoxy-ethoxymethoxy)-2-methyl-propan-1-one 
• 188444-10-2 (S)-3-Hydroxy-2-(4-methoxy-benzylsulfanyl)-2-methyl-propionic acid ethyl ester 

Relevant academic research and scientific papers

Asymmetric synthesis of 5,5-disubstituted thiotetronic acids using an allyl xanthate to dithiocarbonate rearrangement: Total synthesis of (55)-thiolactomycin with revision of the absolute configuration of the natural product

An asymmetric synthesis of thiotetronic acids related to the antibiotics thiolactomycin 1 and thiotetromycin 2 has been developed in which the key step is a stereoselective [3.3]-rearrangement of an allyl xanthate to the corresponding dithiocarbonate. Thu