1888-90-0

Basic information

• Product Name: 3-methylidenecyclohexene
• Synonyms: 3-Methylenecyclohexene; Cyclohexene, 3-methylene-
• CAS NO: 1888-90-0
• Molecular Formula: C₇H₁₀
• Molecular Weight: 94.1543
• Mol File: 1888-90-0.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 114.7°C at 760 mmHg
• Flash Point: 3.5°C
• Density: 0.82g/cm³
• Vapor Pressure: 23.3mmHg at 25°C
• Refractive Index: 1.472
• CAS DataBase Reference: 3-methylidenecyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methylidenecyclohexene(1888-90-0)
• EPA Substance Registry System: 3-methylidenecyclohexene(1888-90-0)

Safety Data

• Hazardous Substances Data: 1888-90-0(Hazardous Substances Data)

Upstream product

• 31171-59-2 N,N-dimethyl-1-cyclohexenylmethylamine 
• 2931-14-8 (4ar,8at)-hexahydro-1,3-benzodioxine 
• 109042-66-2 (+/-)-trimethyl-(trans-2-trimethylammoniomethyl-cyclohexyl)-ammonium; diiodide 
• 108776-78-9 {trans-2-[(dimethyl-oxy-amino)-methyl]-cyclohexyl}-dimethyl-amine oxide 
• 34942-89-7 3-<(acetyloxy)methyl>cyclohexene 
• 110-83-8 cyclohexene 
• 33867-02-6 1-chloromethylcyclohexene 
• 108296-73-7 C₇H₁₂Pt(Cl)4 
• 2568-17-4 bicyclo[3.3.1]nonan-2-one 
• 1521-51-3 rac-3-bromocyclohexene 
• 40391-15-9 methyl N-(2-cyclohexen-1-ylmethyl)carbamate 
• 58714-95-7 2-cyclohexene-1-methanamine 
• 13048-17-4 cyclohex-2-enecarbonitrile 
• 103668-33-3 3-hydroxymethylcyclohexene 

Downstream Products

• 108125-75-3 Cyclohexen-⁽¹⁾-ylmethyl-p-tolylthioether 
• 104190-00-3 2-methylene-7-oxabicyclo<4.1.0>heptane 
• 84099-15-0 N-(3-methyl-2-cyclohexenyl)aniline 
• 591-49-1 1-methylcyclohex-1-ene 
• 591-48-0 3-methyl-1-cyclohexene 
• 591-47-9 4-methylcyclohexene 
• 82166-21-0 methyl cyclohexane 
• 102683-83-0 3-Bromo-3-bromomethanesulfonylmethyl-cyclohexene 

Relevant articles and documents

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Palladium-catalyzed regio- and enantioselective fluorination of acyclic allylic halides

This report describes the Pd(0)-catalyzed fluorination of linear allylic chlorides and bromides, yielding branched allylic fluorides in high selectivity. Many of the significant synthetic limitations previously associated with the preparation of these products are overcome by this catalytic method. We also demonstrate that a chiral bisphosphine-ligated palladium catalyst enables highly enantioselective access to a class of branched allylic fluorides that can be readily diversified to valuable fluorinated products.

Thermal reactions of anti- and syn-dispiro[5.0.5.2]tetradeca-1,8-dienes: Stereomutation and fragmentation to 3-methylenecyclohexenes. Entropy-dictated product ratios from diradical intermediates?

A series of cyclobutanes substituted 1,2- by polyenes of increasing radical-stabilizing power has been investigated to test the proposition that stabilization energies obtained independently from apposite, cis,-trans geometric isomerizations can be succes

Reaction of cyclic allylic acetates with aliphatic alcohols in the presence of cerium(III) chloride

The reactions of selected allylic acetates with methanol, ethanol, n-propyl alcohol, isopropyl alcohol and tert-butyl alcohol in the presence of catalytic amounts of cerium(III) chloride are described. Allylic alkyl ethers, bis-allylic ethers and 1,3-dienes were obtained depending on the structure of the acetates.