18899-87-1Relevant academic research and scientific papers
FIRST-ROW TRANSITION METAL HYDROGENATION AND HYDROSILYLATION CATALYSTS
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Paragraph 00296-00297, (2015/01/09)
Transition metal compounds, and specifically transition metal compounds having a tetradentate and/or pentadentate supporting ligand are described, together with methods for the preparation thereof and the use of such compounds as hydrogenation and/or hydrosilylation catalysts.
Catalytic hydrosilylation of alkenes by iron complexes containing terpyridine derivatives as ancillary ligands
Kamata, Kouji,Suzuki, Atsuko,Nakai, Yuta,Nakazawa, Hiroshi
scheme or table, p. 3825 - 3828 (2012/07/02)
Iron complexes formulated as Fe(terpy)X2 (terpy = 2,2′:6′,2 -terpyridine derivatives; X = Cl, Br) were prepared and their catalytic activities for hydrosilylation of olefin with hydrosilane were examined. Although Fe(terpy)X2 did not
Rare-earth metal alkyl and hydride complexes stabilized by a cyclen-derived [NNNN] macrocyclic ancillary ligand
Ohashi, Masato,Konkol, Marcin,Del Rosal, Iker,Poteau, Romuald,Maron, Laurent,Okuda, Jun
, p. 6920 - 6921 (2008/12/20)
A trinuclear rare-earth metal hydride complex was synthesized from the dialkyl complex supported by a monoanionic [NNNN] macrocycle and shown to catalyze the hydrosilylation of olefins efficiently. Copyright
Hydrosilylation of olefins with monosilane in the presence of lithium aluminum hydride
Kobayashi, Mineo,Itoh, Masayoshi
, p. 1013 - 1014 (2007/10/03)
Hydrosilylation reactions of 1-hexene and ethylene with SiH4 occurs in the presence of LiAlH4 as a catalyst. Hexylsilane and dihexylsilane were produced from 1-hexene and SiH4. Ethylsilane was produced from ethylene and SiH4. The reaction mechanism involving SiH4 and the alkyl anion, which is formed by the interaction between LiAlH4 and the olefin, has been proposed.
