189031-66-1Relevant articles and documents
Preference of Ruthenium-Based Metathesis Catalysts toward Z- and E-Alkenes as a Guide for Selective Reactions to Alkene Stereoisomers
Lee, Jihong,Kim, Kyung Hwan,Lee, Ok Suk,Choi, Tae-Lim,Lee, Hee-Seung,Ihee, Hyotcherl,Sohn, Jeong-Hun
, p. 7591 - 7596 (2016/09/09)
As a guide for selective reactions toward either Z- or E-alkene in a metathesis reaction, the relative preference of metathesis Ru catalysts for each stereoisomer was determined by a method using time-dependent fluorescence quenching. We found that Ru-1 p
Ti-catalyzed straightforward synthesis of exocyclic allenes
Munoz-Bascon, Juan,Hernandez-Cervantes, Carmen,Padial, Natalia M.,Alvarez-Corral, Miriam,Rosales, Antonio,Rodriguez-Garcia, Ignacio,Oltra, J. Enrique
supporting information, p. 801 - 810 (2014/01/23)
Exocyclic allenes constitute useful building blocks in organic synthesis and have recently been identified as key intermediates in the synthesis of natural products. Here the first general method for the most straightforward synthesis of exocyclic allenes
Secondary phosphine oxide-gold(I) complexes and their first application in catalysis
Schroeder, Felix,Tugny, Coralie,Salanouve, Elise,Clavier, Herve,Giordano, Laurent,Moraleda, Delphine,Gimbert, Yves,Mouries-Mansuy, Virginie,Goddard, Jean-Philippe,Fensterbank, Louis
supporting information, p. 4051 - 4056 (2014/10/15)
A series of new secondary phosphine oxide (SPO)-gold(I) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O-H···Cl hydrogen bonds. Their first use in homogeneous catalysis