189031-67-2Relevant academic research and scientific papers
On the faciality of intramolecular Palladium(0)-Catalysed 'metallo-ene-type' cyclisations
Oppolzer, Wolfgang,Stammen, Blanda
, p. 3577 - 3586 (2007/10/03)
The palladium-calalysed 'metallo-ene' step in a cyclisation/β-elimination reaction sequence has been shown to be suprafacial with respect to the olefinic component. This reaction has been applied to the synthesis of a trisubstituted exocyclic alkenyl pyrrolidine with complete stereocontrol.
