18918-52-0Relevant academic research and scientific papers
Synthesis of glucopyranosyl amides using polymer-supported reagents
Root, Yuriko Y.,Bailor, Maximillian S.,Norris, Peter
, p. 2499 - 2506 (2004)
2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl azide reacts efficiently with polymer-supported triphenylphosphine and various acid chlorides to yield glucopyranosyl amides with retention of the β-gluco stereochemistry.
Application of bis(diphenylphosphino)ethane (DPPE) in Staudinger-type N-glycopyranosyl amide synthesis
Temelkoff, David P.,Smith, Craig R.,Kibler, Daniel A.,McKee, Shawn,Duncan, Sara J.,Zeller, Matthias,Hunsen, Mo,Norris, Peter
, p. 1645 - 1656 (2007/10/03)
Bis(diphenylphosphino)ethane (DPPE) reacts with pyranosyl azides derived from d-glucose and d-glucuronic acid in the presence of acid chlorides to yield the corresponding glycosyl amides. Reaction rates are comparable to those with triphenylphosphine, how
An easy access to anomeric glycosyl amides and imines (Schiff bases) via transformation of glycopyranosyl trimethylphosphinimides
Kovács, László,Osz, Erzsébet,Domokos, Valéria,Holzer, Wolfgang,Gy?rgydeák, Zoltán
, p. 4609 - 4621 (2007/10/03)
The preparation and application of anomeric glycosyl phosphinimides in preparative synthesis were studied. Starting from the appropriate glycosyl azides and trialkyl or triaryl phosphines, the corresponding phosphinimides were obtained by modified Staudin
