189636-73-5

Basic information

• Product Name: 3-Oxo-butyric acid (1R,3R)-3-(cyclohex-1-enyloxy)-1-methyl-butyl ester
• Synonyms: 3-Oxo-butyric acid (1R,3R)-3-(cyclohex-1-enyloxy)-1-methyl-butyl ester
• CAS NO: 189636-73-5
• Molecular Weight: 268.353
• Mol File: 189636-73-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Oxo-butyric acid (1R,3R)-3-(cyclohex-1-enyloxy)-1-methyl-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxo-butyric acid (1R,3R)-3-(cyclohex-1-enyloxy)-1-methyl-butyl ester(189636-73-5)
• EPA Substance Registry System: 3-Oxo-butyric acid (1R,3R)-3-(cyclohex-1-enyloxy)-1-methyl-butyl ester(189636-73-5)

Safety Data

• Hazardous Substances Data: 189636-73-5(Hazardous Substances Data)

Upstream product

• 42075-32-1 (2R,4R)-pentanediol 
• 108-94-1 cyclohexanone 
• 121898-55-3 (2R,4R)-4-(cyclohex-1-en-1-yloxy)pentan-2-ol 
• 105-45-3 acetoacetic acid methyl ester 
• 674-82-8 4-methyleneoxetan-2-one 
• 129098-50-6 (2R,4R)-2,4-dimethyl-1,5-dioxaspiro<5.5>undecane 

Downstream Products

• 189636-75-7 Diazo-acetic acid (1R,3R)-3-(cyclohex-1-enyloxy)-1-methyl-butyl ester 
• 36302-36-0 (1S)-ethyl (2-oxocyclohexyl)acetate 

Relevant articles and documents

Diastereo-differentiating intramolecular cyclopropanations of prochiral olefins and a diazo ester linked by optically active 2,4-pentanediol

Intramolecular cyclopropanation of 3, the substrate having a chiral auxiliary as a linking bridge between a diazo ester and cyclohexene, was found to give the cyclopropane 4 having over 99% diastereomeric excess (d.e.) in 91.5% yield. The reaction was als

Temperature-independent stereocontrolled [2+2] cycloaddition. Potential of the 2,4-pentanediol tether in asymmetric reactions as a differential activation entropy promoter

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