189824-33-7Relevant academic research and scientific papers
Synthesis of [1.1.1]Propellanes by Cyclization of 3-Alkylidenecyclobutylidenes
Kenndoff, Monika,Singer, Andrea,Szeimies, Guenter
, p. 217 - 232 (1997)
Starting from tricyclo[3.1.0.02,6]hexane 5 and 1-bromobicyclo[1.1.0]butane 6, a series of [1.1.1]propellanes 15 and 21 has been synthesized which carry alkyl, aryl, alkenyl, and alkynyl groups. Propellane formation proceeded via 1-bromo-1-chlor
