Synthesis of [1.1.1]Propellanes by Cyclization of 3-Alkylidenecyclobutylidenes

DOI: 10.1002/prac.19973390141

Source and publish data:

Advanced Synthesis and Catalysis p. 217 - 232 (1997)

Update date:2022-09-26

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Authors:

Kenndoff, Monika

Singer, Andrea

Szeimies, Guenter

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Article abstract of DOI:10.1002/prac.19973390141

Starting from tricyclo[3.1.0.0^2,6]hexane 5 and 1-bromobicyclo[1.1.0]butane 6, a series of [1.1.1]propellanes 15 and 21 has been synthesized which carry alkyl, aryl, alkenyl, and alkynyl groups. Propellane formation proceeded via 1-bromo-1-chlor

Full text of DOI:10.1002/prac.19973390141

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