190070-14-5Relevant academic research and scientific papers
A facile synthesis of 4-(trialkylmethyl)anilines by the reaction of 4- (trifluoromethyl)aniline with Grignard reagents
Lin, Shou-Yuan,Hojjat, Maryam,Strekowski, Lucjan
, p. 1975 - 1980 (1997)
The treatment of 4-(trifluoromethyl)aniline (7) with primary Grignard reagents in ether yields the title products 14 (50-75%). A mechanistic pathway involves a series of fluoride elimination reactions followed by addition of the Grignard reagent to the resultant nonaromatic intermediate after each elimination step.
Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom
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Page/Page column 36, (2011/02/18)
The present invention provides an article of manufacture formed from a substrate and a benzazoloporphyrazine bound to the substrate. The article may take a variety of different forms and may be for example an electrochromic display, a molecular capacitor, a battery, a solar cell, or a molecular memory device. Methods of making such articles, along with compounds, methods and intermediates useful for making such benzazoloporphyrazines, are also described.
Multypodal tethers for high-density attachment of redox-active moieties to substrates
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, (2008/06/13)
This invention provides redox-active molecules attached to polypodal (e.g., bipodal, tripodal, quadrapodal, pentapodal, etc.) tethers that can be used for attachment of the redox-active molecules to a substrate (e.g., an electrode). The tethered redox-active molecules are useful for the fabrication of memory devices.
A compact all-carbon tripodal tether affords high coverage of porphyrins on silicon surfaces
Padmaja, Kisari,Wei, Lingyun,Lindsey, Jonathan S.,Bocian, David F.
, p. 7972 - 7978 (2007/10/03)
Redox-active molecules designed to give high charge density on electroactive surfaces are essential for applications in molecular information storage. To achieve a small molecular footprint and thereby high surface charge density, a compound consisting of
