Synthetic Communications p. 1975 - 1980 (1997)
Update date:2022-08-03
Topics:
Lin, Shou-Yuan
Hojjat, Maryam
Strekowski, Lucjan
The treatment of 4-(trifluoromethyl)aniline (7) with primary Grignard reagents in ether yields the title products 14 (50-75%). A mechanistic pathway involves a series of fluoride elimination reactions followed by addition of the Grignard reagent to the resultant nonaromatic intermediate after each elimination step.
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