190080-50-3Relevant academic research and scientific papers
Functionalized alkynyl-chlorogermanes: Hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation
Honacker, Christian,Qu, Zheng-Wang,Tannert, Jens,Layh, Marcus,Hepp, Alexander,Grimme, Stefan,Uhl, Werner
, p. 6159 - 6174 (2016)
Treatment of alkynyl-arylchlorogermanes ArylnGe(Cl)(C≡C-tBu)3-n (n = 1, 2) with HMtBu2 (M = Al, Ga) yielded mixed Al or Ga alkenyl-alkynylchlorogermanes via hydrometallation reactions. Intramolecular
New (2,4,6-triisopropylphenyl) hydro-, halo- and hydrohalogermanes
Chaubon,Dittrich,Escudie,Ramdane,Ranaivonjatovo,Satge
, p. 519 - 533 (2008/10/09)
New hydro-, halo- and hydrohalogermanes of the types IsGeH3-nCln (n = 0, 1, 3, Is = 2,4,6-triisopropylphenyl) and Is(R)GeH2-nXn (n = 0 or 2, X = Cl, F), potential precursors of stable, low-coordinated species of germanium, have been synthesized. All of them are substituted by at least one bulky 2,4,6-triisopropylphenyl group, R being a second Is group, a mesityl, a pentamethylcyclopentadienyl or a fluorenyl group.
