190258-39-0Relevant academic research and scientific papers
Au-catalyzed intramolecular hydroalkoxylation of gem-difluorinated alkynols
Hamel, Jean-Denys,Paquin, Jean-Fran?ois
, p. 11 - 23 (2018/10/20)
The intramolecular hydroalkoxylation of gem-difluorinated alkynols was found possible under Au catalysis, allowing for the preparation of a series of fluorinated heterocycles. The nature of the solvent was found to be especially critical in the cyclizatio
Formation of Angularly-Fused Triquinanes by Successive Use of the Pauson-Khand Reaction and Radical Closure
Clive, Derrick L. J.,Cole, Derek C.,Tao, Yong
, p. 1396 - 1406 (2007/10/02)
Angularly-fused triquinanes (see Table 1) are accessible by sequential use of the Pauson-Khand reaction and radical cyclization.The Pauson-Khand step works in the presence of homolyzable bonds, such as C-Br and C-SePh.The method seems best suited to the p
