19078-76-3Relevant academic research and scientific papers
Light-mediated dual phosphine-/copper-catalyzed atom transfer radical addition reaction
Fedorov, Oleg V.,Scherbinina, Sofya I.,Levin, Vitalij V.,Dilman, Alexander D.
, p. 11068 - 11079 (2019/09/30)
The atom transfer radical addition reaction catalyzed by triphenylphosphine and copper(I) halide is described. The reaction proceeds under irradiation with 365 nm light using a light-emitting diode and was performed in regular glassware. The proposed mech
Intramolecular Cyclization of Acyl Radicals onto the Azido Group: A New Radical Approach to Cyclized Lactams
Benati, Luisa,Leardini, Rino,Minozzi, Matteo,Nanni, Daniele,Spagnolo, Piero,Strazzari, Samantha,Zanardi, Giuseppe
, p. 3079 - 3081 (2007/10/03)
(Equation Presented) Reagents: i, Bu3SnH/AlBN; ii, (TMS)3SiH/AlBN. Aryl- and alkyl-derived azidoacyl radicals, generated from thiolesters by intramolecular homolytic substitution at the sulfur, can undergo five- and six-membered cyclization onto the azido moiety to give cyclized lactams.
