1908-87-8

Usage

Uses

vulcanzing agent for CR

InChI:InChI=1/C4H7NS2/c1-5-2-3-7-4(5)6/h2-3H2,1H3

Upstream product

• 109-83-1 (2-hydroxyethyl)(methyl)amine 
• 75-15-0 carbon disulfide 
• 1630-99-5 2-(methylimino)-1,3-dithiolane 

Downstream Products

• 91426-53-8 3-methyl-thiazolidin-2-one benzoylhydrazone 
• 30760-48-6 3-methyl-2-methylsulfanyl-4,5-dihydro-1,3-thiazolium iodide 
• 61681-27-4 [5,5-dimethyl-3-(3-methyl-thiazolidin-2-ylidenemethyl)-cyclohex-2-enylidene]-malononitrile 
• 108487-24-7 3-methyl-2-phenacylmercapto-4,5-dihydro-thiazolium; bromide 

Relevant academic research and scientific papers

[Ag{S2CNR(C2H4OH)}] as Single-Source Precursor for Ag2S - Synthesis, Decomposition Mechanism, and Deposition Studies

Silver(I) dithiocarbamates [Ag{S2CNR(C2H4OH)}] (3a, R = Me; 3b, R = Bu) were accessible by the reaction of AgNO3 with K{S2CNR(C2H4OH)} (2a, R = Me; 2b, R = Bu). Alternatively, 3b could be prepared by the condensation of CS2 and Ag2O with NHBu(C2H4OH) (1b). The thermal behavior of 3 was studied by thermogravimetric (TG) analysis. A two-step decomposition process leads to the formation of α-Ag2S, as evidenced by X-ray powder diffraction studies. A decomposition mechanism of 3a to form Ag2S through the release of 3-methyloxazolidine-2-thione is discussed based on TG-MS, GC-MS, and NMR experiments. Because of the better solubility of 3b, this complex was tested for Ag2S spin-coating deposition studies on different substrates (SiO2/Si, TiN/SiO2/Si, glass) with subsequent annealing at 450 °C under a N2 atmosphere. Film thickness, composition, and morphology of the as-deposited films were determined by XRD, SEM, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy, which showed the formation of 200 nm thick, conformal, adherent, monoclinic α-Ag2S layers.

Synthesis and biological evaluation of thiazolidine-2-one 1,1-dioxide as inhibitors of Escherichia coli β-ketoacyl-ACP-synthase III (FabH)

A series of cyclic sulfones has been synthesized and their activity against β-ketoacyl-ACP-synthase III (FabH) has been investigated. The compounds are selectively active against Escherichia coli FabH (ecFabH), but not Mycobacterium tuberculosis FabH (mtFabH) or Plasmodium falciparum KASIII (PfKASIII). The activity against ecFabH ranges from 0.9 to >100 μM and follows a consistent general SAR trend. Many of the compounds were shown to have antimalarial activity against chloroquine (CQ)-sensitive (D6) P. falciparum (IC50 = 5.3 μM for the most potent inhibitor) and some were active against E. coli (MIC = 6.6 μg/ml for the most potent inhibitor).

PREPARATION AND REACTIONS OF NOVEL μ-OXO-BISANTIMONY AMINOALKOXIDE

Novel μ-oxo-bis(diphenylhydroxyantimony) di (1) was obtained in the reaction of triphenylstibine oxide and 2-(methylamino)ethanol.Cyclic urethane derivatives were obtained by the reaction of 1 with CO2 or CS2 in good yields.

Process for the production of thiazoline-2-thiones

One-pot process for producing thiazoline-2-thiones by reacting corresponding aminoethanols with thionylchloride, heating the resulting product and reacting it subsequently with carbon disulphide.