1908-87-8

Basic information

• Product Name: 3-methylthiazolidine-2-thione
• Synonyms: 3-methylthiazolidine-2-thione;2-Thiazolidinethione, 3-methyl-;3-methyl-2-thiazolidinethion;3-methyl-1,3-thiazolidine-2-thione;ACTOR- MTT;chloroprene rubber vulcanizing agent;MTT-80;Thiazolidinethione
• CAS NO: 1908-87-8
• Molecular Formula: C₄H₇NS₂
• Molecular Weight: 133.23508
• EINECS: 217-614-1
• Product Categories: rubber additive;rubber auxiliary;vulcanizing agent;crosslink agent
• Mol File: 1908-87-8.mol
• Article Data: 4

Chemical Properties

• Melting Point: 68-69 °C
• Boiling Point: 189.7 °C at 760 mmHg
• Flash Point: 68.5 °C
• Appearance: /
• Density: 1.3g/cm³
• Vapor Pressure: 0.562mmHg at 25°C
• Refractive Index: 1.658
• Storage Temp.: 2-8°C
• PKA: 0.81±0.20(Predicted)
• Water Solubility: 3.56g/L at 30℃
• CAS DataBase Reference: 3-methylthiazolidine-2-thione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methylthiazolidine-2-thione(1908-87-8)
• EPA Substance Registry System: 3-methylthiazolidine-2-thione(1908-87-8)

Safety Data

• Hazardous Substances Data: 1908-87-8(Hazardous Substances Data)

Usage

Uses

vulcanzing agent for CR

InChI:InChI=1/C4H7NS2/c1-5-2-3-7-4(5)6/h2-3H2,1H3

Upstream product

• 109-83-1 (2-hydroxyethyl)(methyl)amine 
• 75-15-0 carbon disulfide 
• 1630-99-5 2-(methylimino)-1,3-dithiolane 

Downstream Products

• 91426-53-8 3-methyl-thiazolidin-2-one benzoylhydrazone 
• 30760-48-6 3-methyl-2-methylsulfanyl-4,5-dihydro-1,3-thiazolium iodide 
• 61681-27-4 [5,5-dimethyl-3-(3-methyl-thiazolidin-2-ylidenemethyl)-cyclohex-2-enylidene]-malononitrile 
• 108487-24-7 3-methyl-2-phenacylmercapto-4,5-dihydro-thiazolium; bromide 

Relevant articles and documents

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[Ag{S2CNR(C2H4OH)}] as Single-Source Precursor for Ag2S - Synthesis, Decomposition Mechanism, and Deposition Studies

Silver(I) dithiocarbamates [Ag{S2CNR(C2H4OH)}] (3a, R = Me; 3b, R = Bu) were accessible by the reaction of AgNO3 with K{S2CNR(C2H4OH)} (2a, R = Me; 2b, R = Bu). Alternatively, 3b could be prepared by the condensation of CS2 and Ag2O with NHBu(C2H4OH) (1b). The thermal behavior of 3 was studied by thermogravimetric (TG) analysis. A two-step decomposition process leads to the formation of α-Ag2S, as evidenced by X-ray powder diffraction studies. A decomposition mechanism of 3a to form Ag2S through the release of 3-methyloxazolidine-2-thione is discussed based on TG-MS, GC-MS, and NMR experiments. Because of the better solubility of 3b, this complex was tested for Ag2S spin-coating deposition studies on different substrates (SiO2/Si, TiN/SiO2/Si, glass) with subsequent annealing at 450 °C under a N2 atmosphere. Film thickness, composition, and morphology of the as-deposited films were determined by XRD, SEM, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy, which showed the formation of 200 nm thick, conformal, adherent, monoclinic α-Ag2S layers.

PREPARATION AND REACTIONS OF NOVEL μ-OXO-BISANTIMONY AMINOALKOXIDE

Novel μ-oxo-bis(diphenylhydroxyantimony) di (1) was obtained in the reaction of triphenylstibine oxide and 2-(methylamino)ethanol.Cyclic urethane derivatives were obtained by the reaction of 1 with CO2 or CS2 in good yields.