19088-50-7Relevant academic research and scientific papers
Selective Acid-Catalyzed Hydroarylation of Nonactivated Alkenes with Aniline Assisted by Hexafluoroisopropanol
De Oliveira Vigier, Karine,Humblot, Anaelle,Jér?me, Fran?ois,Jiang, Fan,Peng, Gongming,Pera-Titus, Marc,Wischert, Raphael
, p. 17896 - 17905 (2021/12/13)
The catalytic hydroarylation of nonactivated alkenes with aniline is a reaction of high interest, aiming at providing C-functionalized aniline derivatives that are important precursors for the fabrication of polyurethanes. However, this reaction remains a
Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins
Zhu, Kailong,Shaver, Michael P.,Thomas, Stephen P.
supporting information, p. 977 - 980 (2016/04/20)
A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).
