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2-IODO-2-METHYLBUTANE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

594-38-7

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594-38-7 Usage

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 6441, 1987 DOI: 10.1016/S0040-4039(00)96882-5

Check Digit Verification of cas no

The CAS Registry Mumber 594-38-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,9 and 4 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 594-38:
(5*5)+(4*9)+(3*4)+(2*3)+(1*8)=87
87 % 10 = 7
So 594-38-7 is a valid CAS Registry Number.
InChI:InChI=1/C5H11I/c1-4-5(2,3)6/h4H2,1-3H3

594-38-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-IODO-2-METHYLBUTANE

1.2 Other means of identification

Product number -
Other names Butane,2-iodo-2-methyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:594-38-7 SDS

594-38-7Relevant academic research and scientific papers

Temperature dependence of pentyl nitrate formation from the reaction of pentyl peroxy radicals with NO

Cassanelli, Paola,Fox, David J.,Cox, R. Anthony

, p. 4332 - 4337 (2007)

Alkyl nitrate yields from the reaction of 1-pentyl, 2-pentyl and 2-methyl-2-butyl peroxy radicals with NO have been determined over the temperature range (261-305 K) and at 1 bar pressure from the photo-oxidation of the iodoalkane precursors in air-NO mixtures. Yields were observed to increase with decreasing temperature and, contrary to previous observations, along the series primary secondary ? tertiary. Our results suggests a significant temperature dependence for the formation of nitrates from the reaction of pentyl peroxy radicals with NO and represent an extension in the temperature range over which this reaction has been studied experimentally in the past. the Owner Societies.

Reductive Ni-catalysis for stereoselective carboarylation of terminal aryl alkynes

Maiti, Saikat,Rhlee, Joon Ho

supporting information, p. 11346 - 11349 (2021/11/09)

Stereoselective dicarbofunctionalization of terminal aryl alkynes has been achieved through reductive Ni-catalysis. The exclusive regioselective andanti-addition selective alkylarylation of terminal alkynes is accomplished using alkyl iodide and aryl iodide as electrophilic coupling partners in the presence of NiBr2as the catalyst and Mn as an inexpensive reductant.

Determination and interpretation of second order rate constants for the addition of hydrogen halides to alkenes

Borgeaud, Robert,Newman, Henry,Schelpe, Arabella,Vasco, Veronica,Peter Hughes

, p. 810 - 813 (2007/10/03)

An extensive range of second order rate constants for the addition of hydrogen halides to alkenes in 98% v/v ethanoic acid (acetic acid)-water have been obtained by conductivity measurements. The rate constants are in the expected order of HF HCl HBr HI. The rates with different alkenes cannot be rationalised solely by a consideration of carbocation stability and it has been necessary to consider steric effects in order to explain the observed order.

Convenient, in situ generation of anhydrous hydrogen iodide for the preparation of α-glycosyl iodides and vicinal lodohydrins and for the catalysis of Ferrier glycosylation

Chervin, Stephanie M.,Abada, Paolo,Koreeda, Masato

, p. 369 - 372 (2007/10/03)

(matrix presented) Anhydrous hydrogen iodide is generated in situ by the reaction of solid iodine and a thiol. The HI thus generated has been employed for the efficient preparation of α-glycosyl iodides and vicinal iodohydrins from the corresponding glycosyl acetates and epoxides, respectively, and for Ferrier glycosylation of alcohols and thiols.

Direct Conversion of Alcohols into the Corresponding Iodides

Joseph, Reni,Pallan, S. Pradeep,Sudalai, A.,Ravindranathan, T.

, p. 609 - 612 (2007/10/02)

A mild and effective procedure for directly converting secondary, tertiary and benzylic alcohols into the corresponding iodides is described using I2 in refluxing petroleum ether.The reaction proceeds with inversion of configuration.

Finkelstein Reaction with Aqueous Hydrogen Halides Efficiently Catalysed by Lipophilic Quarternary Onium Salts

Landini, Dario,Albanese, Domenico,Mottadelli, Sabrina,Penso, Michele

, p. 2309 - 2312 (2007/10/02)

The rate of halogen metathesis between halogenoalkanes RX 1-4 (X = F, Cl, Br, I) and aqueous concentrated hydrogen halides HY (Y = Cl, Br, I) is strongly accelerated under phase-transfer catalysis conditions, without solvent.The amount and nature of the nucleophilic species in the organic phase were determined.

EINE EINFACHE METHODE ZUR DARSTELLUNG TERTIAERER IODIDE

Martinez, A. Garcia,Alvarez, R. Martinez,Vilar, E. Teso,Fraile, A. Garcia,Barcina, J. Osio,et al

, p. 6441 - 6442 (2007/10/02)

Hindered alkyl iodides may be prepared conveniently by treatment of the corresponding alcohols with magnesium iodide in n-pentane.

A Convenient Method for the Preparation of Highly Pure t-Alkyl Bromides and Iodides

Masada, Hiromitsu,Murotani, Yoshiharu

, p. 1181 - 1182 (2007/10/02)

Highly pure (99-100 percent) t-butyl and t-pentyl bromides and iodides, and 3-bromo-3-ethylpentane were readily prepared in 83-95 percent yields by the reactions of the corresponding alcohols with hydrobromic or hydroiodic acid, using lithium or calcium halide.The metal halides remarkably increased the yield and the purity of the products.

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