190901-33-8Relevant articles and documents
Hypervalent iodine oxidation of o-aminochalcones: A novel synthesis of 3-(β-styryl)-2,1-benzisoxazoles
Prakash, Om,Saini, Rajesh K.,Singh, Shiv P.,Varma, Rajender S.
, p. 3147 - 3150 (1997)
Hypervalent iodine oxidation of o-aminochalcones using C6H5I(OAc)2-KOH/MeOH leads to a novel and useful route for the synthesis of 3-(β-styryl)-2,1-benzisoxazoles. A plausible mechanism for this novel rearrangement is proposed.
Gold-Catalyzed C-H Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acylindoles
Jin, Hongming,Huang, Long,Xie, Jin,Rudolph, Matthias,Rominger, Frank,Hashmi, A. Stephen K.
supporting information, p. 794 - 797 (2016/02/27)
The gold-catalyzed C-H annulation of anthranil derivatives with alkynes offers a facile, flexible, and atom-economical one-step route to unprotected 7-acylindoles. An intermediate α-imino gold carbene, generated by an intermolecular reaction, promotes ortho-aryl C-H functionalization to afford the target products. The transformation proceeds with a broad range of substrates under mild conditions. Moreover, the obtained functionalized indole products represent a versatile platform for the construction of diverse indolyl frameworks.