19101-48-5Relevant academic research and scientific papers
Nucleophilic aromatic substitution reactions of 1,2-dihydro-1,2-azaborine
Lamm, Ashley N.,Garner III, Edward B.,Dixon, David A.,Liu, Shih-Yuan
, p. 8157 - 8160 (2011/10/03)
Could go either way: The addition of nucleophiles to the parent 1,2-dihydro-1,2-azaborine and subsequent quenching with an electrophile generates novel substituted 1,2-azaborine derivatives (see scheme). Mechanistic studies are consistent with two distinc
Switchable haptotropic migrations of tricarbonylchromium complexes of 1,2-dihydro-2-phenyl-1,2-azaborine
Pan, Jun,Kampf, Jeff W.,Ashe III, Arthur J.
, p. 197 - 202 (2008/10/09)
1,2-Dihydro-2-phenyl-1,2-azaborine (5) reacts with Cr(CO) 3(CH3CN)3 in THF at 50 °C to form the Cr(CO)3 complex 7 in which the chromium is η6-bound to the heterocyclic ring. Heating 7 in THF to 101 °C
1,2-Azaboratabenzene: A heterocyclic π-ligand with an adjustable basicity at nitrogen
Pan, Jun,Kampf, Jeff W.,Ashe III, Arthur J.
, p. 5626 - 5629 (2008/10/09)
1,2-Dihydro-2-phenyl-l,2-azaborine (6a) has been prepared by a multistep synthesis from the readily available 2,2-dibutyl-2,5-dihydro-1-trimethylsilyl- 1H1,2-azastannole (7). Deprotonation of 6a affords 1-phenyl-1,2-azaboratabemene la, which on reaction with [Cp*RuCl]4 gives the sandwich compound 5. 5 has been shown to function as a nucleophilic catalyst for the acylation of benzyl alcohol by phenylethylketene.
