386708-26-5Relevant academic research and scientific papers
1,2-Azaboratabenzene: A heterocyclic π-ligand with an adjustable basicity at nitrogen
Pan, Jun,Kampf, Jeff W.,Ashe III, Arthur J.
, p. 5626 - 5629 (2008/10/09)
1,2-Dihydro-2-phenyl-l,2-azaborine (6a) has been prepared by a multistep synthesis from the readily available 2,2-dibutyl-2,5-dihydro-1-trimethylsilyl- 1H1,2-azastannole (7). Deprotonation of 6a affords 1-phenyl-1,2-azaboratabemene la, which on reaction with [Cp*RuCl]4 gives the sandwich compound 5. 5 has been shown to function as a nucleophilic catalyst for the acylation of benzyl alcohol by phenylethylketene.
Synthesis of 1,2-dihydro-1,2-azaborines and their conversion to tricarbonyl chromium and molybdenum complexes
Ashe III, Arthur J.,Fang, Xiangdong,Fang, Xinggao,Kampf, Jeff W.
, p. 5413 - 5418 (2008/10/08)
1,2-dihydro-1,2-azaborines (1c, 1d, and 1e) have been prepared by the reaction of the corresponding 2,3-dihydro-1H-1,2-azaborol-3-yllithium reagents (1c, 1d, and 1e). The reaction of 1e with Py3Mo(CO)3 and BF3·OEt2/s
