191024-68-7

Upstream product

• 28642-64-0 methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 191024-62-1 Benzoic acid (2R,4aR,6S,7R,8aS)-8-difluoromethylene-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 98-88-4 benzoyl chloride 
• 68366-59-6 (2R,4aR,6S,7R,8aR)-6-methoxy-8-oxo-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine 

Relevant academic research and scientific papers

Highly stereoselective route to aldol products incorporating fluorine containing methyl groups starting from a single D-glucose-derived intermediate

Chiral aldol structures with fluorine modifications on a methyl group have been realized by utilization of the relatively rigid cyclic intermediates from the very common chiral pool compound, D-glucose, leading to attainment of the high diastereoselectivi