191352-07-5

Upstream product

• 191352-10-0 (4R,5R)-3-benzyl-5-(3'-hydroxypropyl)-4-methyl-2-oxazolidinone 
• 100-39-0 benzyl bromide 
• 191352-09-7 (4R,5R)-3-benzyl-5-(3'-benzyloxypropyl)-4-methyl-2-oxazolidinone 
• 187745-52-4 (+)-(4R,5R)-5-(3'-benzyloxypropyl)-4-methyl-2-oxazolidinone 

Downstream Products

• 191352-12-2 (4R,5R)-3-Benzyl-5-[(S)-3-hydroxy-14-(tetrahydro-pyran-2-yloxy)-pentadecyl]-4-methyl-oxazolidin-2-one 
• 191352-21-3 (4R,5R)-3-Benzyl-5-[(R)-3-hydroxy-14-(tetrahydro-pyran-2-yloxy)-pentadecyl]-4-methyl-oxazolidin-2-one 

Relevant academic research and scientific papers

Diastereoselective and convergent synthesis of both 11′-epimers of (-)-(2R,3R,6S)-carnavaline

Enantio- and diastereoselective syntheses of both 11′-epimers of (-)-carnavaline 1 have been achieved. Since the configuration of the remote chiral centre in the C-12 side chain of naturally occurring (-)-carnavaline had been unknown and spectroscopic data were not conclusive, an assignment of the 11′S-epimer to the natural product by comparison of the melting points is discussed and complete spectroscopic data are given.