191352-12-2

Upstream product

• 187745-52-4 (+)-(4R,5R)-5-(3'-benzyloxypropyl)-4-methyl-2-oxazolidinone 
• 191352-11-1 (S)-12-(tetrahydropyran-2'-yloxy)-dodecane-2-ol 
• 191352-09-7 (4R,5R)-3-benzyl-5-(3'-benzyloxypropyl)-4-methyl-2-oxazolidinone 
• 191352-10-0 (4R,5R)-3-benzyl-5-(3'-hydroxypropyl)-4-methyl-2-oxazolidinone 
• 165394-46-7 (S)-12-bromo-dodecane-2-ol 
• 165394-45-6 (S)-Dodecane-2,12-diol 
• 100-39-0 benzyl bromide 
• 3937-56-2 1,9-Nonanediol 
• 55362-80-6 9-bromononan-1-ol 
• 55695-90-4 2-(9-bromononyloxy)tetrahydropyran 
• 191352-07-5 (4R,5R)-3-benzyl-4-methyl-5-(3'-oxopropyl)-2-oxazolidinone 
• 191352-06-4 (S)-1-bromo-11-(tetrahydropyran-2'-yloxy)dodecane 

Relevant academic research and scientific papers

Diastereoselective and convergent synthesis of both 11′-epimers of (-)-(2R,3R,6S)-carnavaline

Enantio- and diastereoselective syntheses of both 11′-epimers of (-)-carnavaline 1 have been achieved. Since the configuration of the remote chiral centre in the C-12 side chain of naturally occurring (-)-carnavaline had been unknown and spectroscopic data were not conclusive, an assignment of the 11′S-epimer to the natural product by comparison of the melting points is discussed and complete spectroscopic data are given.