191354-85-5

Upstream product

• 98-88-4 benzoyl chloride 
• 109582-31-2 (2S,3S)-1,4-bis(phenylmethoxy)-2,3-diaminobutane 
• 133268-20-9 D-2,3-diazido-1,4-dibenzoylbutane 
• 17137-55-2 (2S,3S)-2,3-di(methanesulfonyloxy)-1,4-dibenzyloxybutane 
• 17401-06-8 (2S,3S)-1,4-bis(benzyloxy)-2,3-butanediol 

Downstream Products

• 335162-29-3 (2S,3S)-N,N'-dibenzyl-2,3-diamino-1,4-butanediol 
• 890662-64-3 (1S,6S)-2,7-di(N-benzyl)aza-4,9-dioxabicyclo[4.4.0]decane 
• 890662-66-5 (4S,5S)-4,5-di(hydroxymethyl)-1,3-di(N-benzyl)imidazolidine 
• 263752-07-4 (2S,3S)-2,3-bis(benzoylamino)butane-1,4-diol 

Relevant academic research and scientific papers

Synthesis of new chiral mixed cis-tetraheterodecalines by highly selective cyclization of N,N′-bisalkyl 2,3-diaminobutanediols

Chiral secondary vic-diamines of diaminobutanediols have been efficiently prepared from L-tartaric acid. Their selective cyclization led to cis-tetraheterodecalines having a (1S,6S)-2,7-diaza-4,9-dioxa[4.4.0]decane core system. Georg Thieme Verlag Stuttgart.

Asymmetric cyclopropanation catalyzed by C2-symmetric bi(oxazolines)

C2-symmetric bi(oxazolines) 3a-e were prepared in three steps based on a tartaric-derived vicinal diamine as common precursor. These chiral ligands were studied with respect to their directive influence on the enantioselective copper catalyzed

Efficient synthesis of (2R,3R)- and (2S,3S)-2,3-diaminobutane-1,4-diol and their dibenzyl ethers

(2R,3R)-2,3-Diaminobutane-1,4-diol 6 and its dibenzyl ether 7 were efficiently synthesized starting from L-tartaric acid 1a. The crucial step, debenzylation of intermediate dibenzyloxydiazide 4, was accomplished in good yield by boron trichloride-dimethyl sulfide complex. The enantiomeric series was similarly obtained starting from D-tartaric acid.

Synthesis of new C2-symmetric bioxazoles and application as chiral ligands in asymmetric hydrosilylation

New C2-symmetric chiral (4S,4'S)-bioxazoles 3a and 3b, possessing chirality on their backbone, were synthesized efficiently starting from L-tartaric acid. The structure of 3a was determined by X-ray crystal structure analysis. With these novel