191487-99-7

Upstream product

• 106-24-1 Geraniol 
• 106-28-5 Farnesol 
• 24163-93-7 farnesyl bromide 
• 25974-58-7 4-methoxy-2-(3-methylbut-2-enyl)phenol 
• 56881-53-9 (E,E)-farnesyl phenylsulfone 
• 873-55-2 sodium benzenesulfonate 
• 144705-45-3 2-(2,3-Epoxy-3-methylbutyl)-4-methoxyphenol 
• 191401-69-1 (E)-8-Benzenesulfonyl-2,6-dimethyl-octa-1,6-dien-3-ol 
• 191487-97-5 (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-hydroxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester 
• 191401-72-6 (E)-2-Benzenesulfonyl-7-methoxycarbonyloxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-71-5 (E)-2-Benzenesulfonyl-7-hydroxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-70-4 (E)-2-Benzenesulfonyl-7-hydroxy-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 870-63-3 prenyl bromide 
• 159108-83-5 2-<2-<(methoxycarbonyl)oxy>-3-methylbut-3-enyl>-1-<(methoxycarbonyl)oxy>-4-methoxybenzene 

Downstream Products

• 35890-87-0 2-((2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaenyl)-1,4-benzoquinone 
• 35890-90-5 2-octaprenyl-1,4-hydroquinone 
• 191401-84-0 2-((2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaenyl)-4-methoxyphenol 
• 191488-00-3 4-Methoxy-2-((2E,6E,10E,14E,18E,22E,26E)-5,13,21-tris-benzenesulfonyl-3,7,11,15,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaenyl)-phenol 

Relevant academic research and scientific papers

Total synthesis of polyprenylhydroquinols and benzoquinones

The total synthesis of polyprenylhydroquinols and benzoquinones is described.First, two appropriate aromatic allyl carbonates (moieties with one and two prenyls) and two activated bifunctional terpenyl derivatives (moieties with two and three prenyls) were synthesized.These molecules were then reacted together using a highly regio- and stereoselective coupling with Pd(PPh3)4 as a catalyst.The synthesis was achieved by functional group elimination and formation of quinonic and hydroquinonic moieties. - Keywords: polyprenylbenzoquinol; polyprenylhydroquinone; allylcarbonate; ?-allyl palladium complex