191487-98-6

Basic information

• Product Name: (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester
• Synonyms: (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester
• CAS NO: 191487-98-6
• Molecular Weight: 993.203
• Mol File: 191487-98-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester(191487-98-6)
• EPA Substance Registry System: (3E,7E)-2,10-Bis-benzenesulfonyl-10-((E)-5-methoxycarbonyloxy-2,6-dimethyl-hepta-1,6-dienyl)-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-undeca-3,7-dienedioic acid dimethyl ester(191487-98-6)

Safety Data

• Hazardous Substances Data: 191487-98-6(Hazardous Substances Data)

Upstream product

• 191401-72-6 (E)-2-Benzenesulfonyl-7-methoxycarbonyloxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-71-5 (E)-2-Benzenesulfonyl-7-hydroxy-2-[(E)-4-(5-methoxy-2-methoxycarbonyloxy-phenyl)-2-methyl-but-2-enyl]-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-70-4 (E)-2-Benzenesulfonyl-7-hydroxy-4,8-dimethyl-nona-3,8-dienoic acid methyl ester 
• 191401-69-1 (E)-8-Benzenesulfonyl-2,6-dimethyl-octa-1,6-dien-3-ol 
• 870-63-3 prenyl bromide 
• 159108-83-5 2-<2-<(methoxycarbonyl)oxy>-3-methylbut-3-enyl>-1-<(methoxycarbonyl)oxy>-4-methoxybenzene 
• 159108-82-4 2-(2-hydroxy-3-methyl-3-butenyl)-4-methoxyphenol 
• 144705-45-3 2-(2,3-Epoxy-3-methylbutyl)-4-methoxyphenol 
• 150-76-5 4-methoxy-phenol 
• 74832-85-2 6,7-oxido-3,7-dimethyl-1-(benzenesulfonyl)-(2E)-octene 
• 873-55-2 sodium benzenesulfonate 
• 56691-80-6 geranyl phenyl sulfone 
• 25974-58-7 4-methoxy-2-(3-methylbut-2-enyl)phenol 
• 106-24-1 Geraniol 

Downstream Products

• 191488-00-3 4-Methoxy-2-((2E,6E,10E,14E,18E,22E,26E)-5,13,21-tris-benzenesulfonyl-3,7,11,15,19,23,27,31-octamethyl-dotriaconta-2,6,10,14,18,22,26,30-octaenyl)-phenol 
• 191401-84-0 2-((2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaenyl)-4-methoxyphenol 
• 35890-90-5 2-octaprenyl-1,4-hydroquinone 
• 35890-87-0 2-((2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31-octamethyldotriaconta-2,6,10,14,18,22,26,30-octaenyl)-1,4-benzoquinone 
• 191487-99-7 C₇₃H₉₂O₁₆S₃ 

Relevant articles and documents

Total synthesis of polyprenylhydroquinols and benzoquinones

The total synthesis of polyprenylhydroquinols and benzoquinones is described.First, two appropriate aromatic allyl carbonates (moieties with one and two prenyls) and two activated bifunctional terpenyl derivatives (moieties with two and three prenyls) were synthesized.These molecules were then reacted together using a highly regio- and stereoselective coupling with Pd(PPh3)4 as a catalyst.The synthesis was achieved by functional group elimination and formation of quinonic and hydroquinonic moieties. - Keywords: polyprenylbenzoquinol; polyprenylhydroquinone; allylcarbonate; ?-allyl palladium complex