35890-87-0Relevant academic research and scientific papers
Antioxidant potential of natural and synthesised polyprenylated hydroquinones
Tziveleka, Leto-A,Kourounakis, Angeliki P,Kourounakis, Panos N,Roussis, Vassilios,Vagias, Constantinos
, p. 935 - 939 (2007/10/03)
Metabolites 2-octaprenyl-1,4-hydroquinone (1) and 2-(24-hydroxy)-octaprenyl-1,4-hydroquinone (2), isolated from the sponge Ircinia spinosula, along with eight synthetic derivatives, were evaluated for their antioxidant capacity. The antioxidant potential
Total synthesis of polyprenylhydroquinols and benzoquinones
Bouzbouz, Samir,Kirschleger, Bernard,Villieras, Jean
, p. 67 - 84 (2007/10/03)
The total synthesis of polyprenylhydroquinols and benzoquinones is described.First, two appropriate aromatic allyl carbonates (moieties with one and two prenyls) and two activated bifunctional terpenyl derivatives (moieties with two and three prenyls) were synthesized.These molecules were then reacted together using a highly regio- and stereoselective coupling with Pd(PPh3)4 as a catalyst.The synthesis was achieved by functional group elimination and formation of quinonic and hydroquinonic moieties. - Keywords: polyprenylbenzoquinol; polyprenylhydroquinone; allylcarbonate; ?-allyl palladium complex
