192136-54-2Relevant academic research and scientific papers
Pentaarylfullerenes as noncoordinating cyclopentadienyl anions
Bouwkamp, Marco W.,Meetsma, Auke
, p. 8 - 9 (2009/05/30)
The first example of an early-transition-metal complex involving a pentaarylfullerene was prepared. Instead of half-sandwich complexes, solvent separated ion pairs were obtained in which the pentaarylfullerene moiety acts as noncoordinating cyclopentadien
Synthesis of cationic group 4 metal compounds by protonolysis of amide precursors: Crystal structure of [Ti(NMe2)3(NC5H5)2][BPh4]
Boisson, Christophe,Berthet, Jean Claude,Ephritikhine, Michel,Lance, Monique,Nierlich, Martine
, p. 115 - 119 (2007/10/03)
Protonation of [M(NMe2)4] with NHEt3BPh4 in tetrahydrofuran (THF) gave the cationic compounds [M(NMe2)3(THF)x][BPh4] (M = Ti and x = 1; M = Zr or Hf and x = 2); simila
