192225-81-3Relevant academic research and scientific papers
3H-Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms
Kl?cker, Hans,Tendyck, Jonas C.,Keweloh, Lukas,Hepp, Alexander,Uhl, Werner
, p. 4793 - 4807 (2019/03/13)
A facile method for the efficient synthesis of 3H-phosphaallenes, R?P=C=C(H)?R′, is presented, which comprises treatment of dialkynylphosphines with dialkylaluminium hydrides (hydroalumination) and elimination of aluminium alkynides from intermediate alke
Vanadacyclopropene Phosphane Cp2V(η2-PhC=C)P(C=CPh)Ar
Choukroun, Robert,Miquel, Yannick,Donnadieu, Bruno,Igau, Alain,Blandy, Claudine,Majoral, Jean Pierre
, p. 1795 - 1797 (2008/10/08)
Treatment of the bis(alkynyl)phosphane Ar-P(C=CPh)2 (3) (Ar = 2,4,6-t-Bu3C6H2) with Cp2V gives the vanadacyclopropene phosphane 5, which was characterized by X-ray diffraction. The reactivity of 5 tow
