192573-29-8Relevant articles and documents
Resolution of racemic carboxylic acid derivatives by Ti-TADDOLate mediated esterification reactions a general method for the preparation of enantiopure compounds
Seebach, Dieter,Jaeschke, Georg,Gottwald, Konstanze,Matsuda, Keiji,Formisano, Roberto,Chaplin, David A.,Breuning, Matthias,Bringmann, Gerbard
, p. 7539 - 7556 (2007/10/03)
The Lewis-acid mediated transfer of an alkoxide ligand from the chiral ligand sphere of Ti-TADDOLates 1 to cyclic carboxylic acid derivatives is described. The kinetic resolution of dioxolanones, azlactones and biaryl lactones by the Ti-TADDOLates affords