193279-74-2

Upstream product

• 143-33-9 sodium cyanide 
• 193279-86-6 Methanesulfonic acid (2R,3R,4aR,6S,7R,9S,10aS)-3-benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-ylmethyl ester 
• 193279-85-5 [(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-methanol 
• 193279-66-2 (2S,3R,5R,7S,8R)-2-acetoxymethyl-3,7-bis(benzoyloxy)-5-methyloxocan-2,8-dimethanol 
• 193279-70-8 (E)-4-((4aS,6R,7S,9S,10aR)-2,2,9-Trimethyl-7-triisopropylsilanyloxy-hexahydro-1,3,5-trioxa-benzocycloocten-6-yl)-but-2-en-1-ol 
• 193279-69-5 4-((4aS,6R,7S,9S,10aR)-2,2,9-Trimethyl-7-triisopropylsilanyloxy-hexahydro-1,3,5-trioxa-benzocycloocten-6-yl)-but-2-yn-1-ol 
• 193279-72-0 (E)-3-((4aR,6R,7aS,9R,10R,11aR,12aS)-10-Hydroxy-3,3,6-trimethyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cycloocten-9-yl)-acrylic acid methyl ester 
• 193279-82-2 [(2R,3R)-3-((4aS,6R,7S,9S,10aR)-2,2,9-Trimethyl-7-triisopropylsilanyloxy-hexahydro-1,3,5-trioxa-benzocycloocten-6-ylmethyl)-oxiranyl]-methanol 
• 193279-80-0 (4aS,6R,7S,9R,10aR)-6-Benzyloxymethoxymethyl-2,2,9-trimethyl-octahydro-1,3,5-trioxa-benzocycloocten-7-ol 
• 193279-83-3 (4aR,6R,7aS,9R,10R,11aR,12aS)-9-((E)-3-Hydroxy-propenyl)-3,3,6-trimethyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cycloocten-10-ol 
• 193279-79-7 (2R,3S,5S,7R,8S)-2-Benzyloxymethoxymethyl-8-hydroxymethyl-5-methyl-oxocane-3,7-diol 
• 193279-81-1 ((4aS,6R,7S,9S,10aR)-2,2,9-Trimethyl-7-triisopropylsilanyloxy-hexahydro-1,3,5-trioxa-benzocycloocten-6-yl)-methanol 
• 193279-73-1 (4aR,6R,7aS,9R,10R,11aR,12aS)-10-Benzyloxy-9-((E)-3-benzyloxy-propenyl)-3-(4-methoxy-phenyl)-6-methyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cyclooctene 
• 193279-78-6 C₃₄H₃₈O₉ 

Downstream Products

• 193279-75-3 (E)-4-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-2-methyl-but-2-en-1-ol 
• 193279-88-8 {(2R,3R)-3-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-ylmethyl]-2-methyl-oxiranyl}-methanol 
• 193279-76-4 (2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-decahydro-1,5-dioxa-benzocyclooctene 
• 193279-87-7 (E)-4-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-2-methyl-but-2-enoic acid ethyl ester 

Relevant academic research and scientific papers

Stereocontrolled synthesis of the HIJ ring system of ciguatoxin

Divergent synthesis of the HIJ ring framework 21 of ciguatoxin 1 starting with oxocane 10 is achieved using the palladium- and acid-catalysed cyclization reactions of hydroxy epoxides.