193279-66-2

Upstream product

• 108-05-4 vinyl acetate 
• 98-88-4 benzoyl chloride 

Downstream Products

• 193279-87-7 (E)-4-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-2-methyl-but-2-enoic acid ethyl ester 
• 193279-86-6 Methanesulfonic acid (2R,3R,4aR,6S,7R,9S,10aS)-3-benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-ylmethyl ester 
• 193279-76-4 (2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-decahydro-1,5-dioxa-benzocyclooctene 
• 193279-88-8 {(2R,3R)-3-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-ylmethyl]-2-methyl-oxiranyl}-methanol 
• 193279-75-3 (E)-4-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-2-methyl-but-2-en-1-ol 
• 193279-74-2 [(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-acetonitrile 
• 193279-73-1 (4aR,6R,7aS,9R,10R,11aR,12aS)-10-Benzyloxy-9-((E)-3-benzyloxy-propenyl)-3-(4-methoxy-phenyl)-6-methyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cyclooctene 
• 193279-85-5 [(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-methanol 
• 193279-84-4 (4aR,6R,7aS,9R,10R,11aR,12aS)-10-Benzyloxy-9-((E)-3-benzyloxy-propenyl)-3,3,6-trimethyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cyclooctene 
• 193279-67-3 ((4aS,6R,7S,9S,10aR)-6-Benzyloxymethoxymethyl-2,2,9-trimethyl-hexahydro-1,3,5-trioxa-benzocycloocten-7-yloxy)-triisopropyl-silane 
• 193279-80-0 (4aS,6R,7S,9R,10aR)-6-Benzyloxymethoxymethyl-2,2,9-trimethyl-octahydro-1,3,5-trioxa-benzocycloocten-7-ol 
• 193279-79-7 (2R,3S,5S,7R,8S)-2-Benzyloxymethoxymethyl-8-hydroxymethyl-5-methyl-oxocane-3,7-diol 
• 193279-78-6 C₃₄H₃₈O₉ 

Relevant academic research and scientific papers

Enantioselective synthesis of the medium ring ethers, tetrahydrooxepin, oxocane and hexahydrooxonin, of ciguatoxin. Extensive ring-expansion and chemoenzymatic desymmetrization strategy

The extensive ring-expansion strategy for the synthesis of tetrahydrooxepin, oxocane, and hexahydrooxonin, which correspond to the D(E), I and F rings of ciguatoxin (CTX1B, 1). respectively, has been established. Chemoenzymatic acylation of the meso alcoh