193279-80-0

Upstream product

• 77-76-9 2,2-dimethoxy-propane 
• 193279-79-7 (2R,3S,5S,7R,8S)-2-Benzyloxymethoxymethyl-8-hydroxymethyl-5-methyl-oxocane-3,7-diol 
• 193279-78-6 C₃₄H₃₈O₉ 
• 193279-66-2 (2S,3R,5R,7S,8R)-2-acetoxymethyl-3,7-bis(benzoyloxy)-5-methyloxocan-2,8-dimethanol 
• 3587-60-8 Benzyloxymethyl chloride 
• 108-05-4 vinyl acetate 

Downstream Products

• 193279-67-3 ((4aS,6R,7S,9S,10aR)-6-Benzyloxymethoxymethyl-2,2,9-trimethyl-hexahydro-1,3,5-trioxa-benzocycloocten-7-yloxy)-triisopropyl-silane 
• 193279-87-7 (E)-4-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-2-methyl-but-2-enoic acid ethyl ester 
• 193279-86-6 Methanesulfonic acid (2R,3R,4aR,6S,7R,9S,10aS)-3-benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-ylmethyl ester 
• 193279-76-4 (2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-6-((2R,3R)-3-methyl-3-vinyl-oxiranylmethyl)-decahydro-1,5-dioxa-benzocyclooctene 
• 193279-88-8 {(2R,3R)-3-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-ylmethyl]-2-methyl-oxiranyl}-methanol 
• 193279-75-3 (E)-4-[(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-2-methyl-but-2-en-1-ol 
• 193279-74-2 [(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-acetonitrile 
• 193279-73-1 (4aR,6R,7aS,9R,10R,11aR,12aS)-10-Benzyloxy-9-((E)-3-benzyloxy-propenyl)-3-(4-methoxy-phenyl)-6-methyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cyclooctene 
• 193279-85-5 [(2R,3R,4aR,6S,7R,9S,10aS)-3-Benzyloxy-2-((E)-3-benzyloxy-propenyl)-7-(4-methoxy-benzyloxy)-9-methyl-decahydro-1,5-dioxa-benzocycloocten-6-yl]-methanol 
• 193279-84-4 (4aR,6R,7aS,9R,10R,11aR,12aS)-10-Benzyloxy-9-((E)-3-benzyloxy-propenyl)-3,3,6-trimethyl-decahydro-2,4,8,12-tetraoxa-dibenzo[a,d]cyclooctene 

Relevant academic research and scientific papers

Enantioselective synthesis of the medium ring ethers, tetrahydrooxepin, oxocane and hexahydrooxonin, of ciguatoxin. Extensive ring-expansion and chemoenzymatic desymmetrization strategy

The extensive ring-expansion strategy for the synthesis of tetrahydrooxepin, oxocane, and hexahydrooxonin, which correspond to the D(E), I and F rings of ciguatoxin (CTX1B, 1). respectively, has been established. Chemoenzymatic acylation of the meso alcoh

Stereocontrolled synthesis of the HIJ ring system of ciguatoxin

Divergent synthesis of the HIJ ring framework 21 of ciguatoxin 1 starting with oxocane 10 is achieved using the palladium- and acid-catalysed cyclization reactions of hydroxy epoxides.