193553-77-4Relevant academic research and scientific papers
From sugar allyltins to chiral cyclopentadienes: Radical cyclization of highly oxygenated sugar-derived dienoaldehydes
Mach,Jarosz
, p. 936 - 940 (2007/10/03)
Radical cyclization of unsaturated aldehyde: 2,3,4-tri-O-benzyl-5,6,7,8-tetradeoxy-5(E),6-dieno-oct-D-xylose (2) afforded 1(R)-hydroxy-2(S),3(S),4(R)-tri-O-benzyloxy-5(R)-[prop-1(E)-enyl]-cyclopentane (5); similar reaction of xanthate 7 derived from 2 led to 2(S),3(R),4(R)-tri-O-benzyloxy-5(R)-methyl-cyclopentane (8). The cyclization of other sugar-derived unsaturated aldehydes and xanthates was also studied.
