193979-96-3

Basic information

• Product Name: (S)-4-methyl-benzenesulfinic acid propylideneamide
• Synonyms: (S)-4-methyl-benzenesulfinic acid propylideneamide
• CAS NO: 193979-96-3
• Molecular Weight: 195.285
• Mol File: 193979-96-3.mol

Chemical Properties

• CAS DataBase Reference: (S)-4-methyl-benzenesulfinic acid propylideneamide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-methyl-benzenesulfinic acid propylideneamide(193979-96-3)
• EPA Substance Registry System: (S)-4-methyl-benzenesulfinic acid propylideneamide(193979-96-3)

Safety Data

• Hazardous Substances Data: 193979-96-3(Hazardous Substances Data)

Upstream product

• 123-38-6 propionaldehyde 
• 188447-91-8 (S)-p-toluenesulfinimide 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 

Downstream Products

• 193979-97-4 (2R,3S)-3-Ethyl-2-methyl-1-((S)-toluene-4-sulfinyl)-aziridine-2-carboxylic acid methyl ester 
• 193979-98-5 (2R,3S)-3-Ethyl-2-methyl-1-(toluene-4-sulfonyl)-aziridine-2-carboxylic acid methyl ester 
• 193980-01-7 (2R,3S)-2-Methyl-3-(toluene-4-sulfonylamino)-pentanoic acid 
• 193979-99-6 (2R,3S)-(-)-2-methyl-N-(p-toluenesulfonyl)-3-aminopentanol 
• 596823-43-7 (+)-methyl [(2S,4S,5R,S_S)-5-ethyl-2-phenyl-1-(p-tolylsulfinyl)-1,3-imidazolidin-4-yl]carboxylate 
• 467471-29-0 (+)-(2S,3R,S_S)-2-(benzylamino)-3-(p-tolylsulfinylamino)pentan-1-ol 

Relevant articles and documents

Asymmetric thio-Michael/nucleophilic addition domino reaction with chiral N-sulfinimines

(Chemical Equation Presented) Optically active N-sulfinimines underwent stereoselective Michael/nucleophilic addition domino reaction triggered by magnesium thiolate to give α-phenylthiomethyl-β-(N-sulfinylamino) esters in high diastereomeric excess. The

Stereoselective synthesis of β-substituted β-amino sulfones and sulfonamides via addition of sulfonyl anions to chiral N-sulfinyl imines

A highly stereoselective synthesis of β-amino sulfones and sulfonamides via addition of sulfonyl anions to chiral N-sulfinyl imines is described. The addition reaction proceeds in good yield (75-99%) and stereoselectivity.

Synthesis of enantiopure sulfinimines (Thiooxime S-oxides) catalyzed by Yb(OTf)3 from p-toluenesulfinamide and aldehydes in mild reaction conditions

(Chemical Equation Presented) Enantiomerically pure sulfinimines as important building blocks in the asymmetric synthesis of amine derivatives are prepared in good to excellent yields from chiral p-toluene-sulfinamide with aromatic, heteroaromatic, and al

Aziridine 2-carboxylate ester mediated asymmetric synthesis of α-alkyl β-amino acids

The highly stereoselective ring opening of N-tosylaziridine 2-carboxylate esters with LiAIH4 followed by oxidation of the ensuing syn alcohols results in a highly efficient 4 step asymmetric synthesis of α-methyl β-amino acids from N-sulfinylaziridine 2-carboxylate esters.