19398-89-1

Basic information

• Product Name: TRANS-4-DECENE
• Synonyms: TRANS-4-DECENE;(4E)-4-Decene;(E)-4-C10H20;(E)-4-decene;4-Decene, (E)-;t-4-Decene;trans-dec-4-ene;(E)-dec-4-ene
• CAS NO: 19398-89-1
• Molecular Formula: C₁₀H₂₀
• Molecular Weight: 140.27
• EINECS: 243-034-3
• Mol File: 19398-89-1.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 168-170 °C(lit.)
• Flash Point: 45 °C
• Appearance: /
• Density: 0.740 g/mL at 20 °C(lit.)
• Refractive Index: n20/D 1.424
• CAS DataBase Reference: TRANS-4-DECENE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-4-DECENE(19398-89-1)
• EPA Substance Registry System: TRANS-4-DECENE(19398-89-1)

Safety Data

• Statements: 10
• RIDADR: 1993
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 19398-89-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 154, 1980 DOI: 10.1021/jo01289a030

InChI:InChI=1/C10H20/c1-3-5-7-9-10-8-6-4-2/h7,9H,3-6,8,10H2,1-2H3/b9-7+

Upstream product

• 53248-87-6 cis-4-decene oxide 
• 73881-10-4 (E)-1-bromo-2-hexene 
• 109-67-1 1-penten 
• 1779-51-7 n-butyl(triphenyl)phosphonium bromide 
• 111-27-3 hexan-1-ol 
• 112-37-8 undecylenic acid 
• 546-67-8 lead(IV) tetraacetate 
• 71-43-2 benzene 
• 2384-86-3 4-decyne 
• 872-05-9 1-Decene 
• 19398-88-0 (Z)-dec-4-ene 
• 1942-46-7 5-decyne 
• 102-67-0 tri-n-propylaluminum 
• 60788-60-5 cis-4,5-epoxydecane 

Downstream Products

• 592-99-4 4-octene 
• 29493-00-3 dodec-6-ene 
• 142-62-1 hexanoic acid 
• 107-92-6 butyric acid 

Relevant articles and documents

-

-

Catalytic, oxidant-free, direct olefination of alcohols using Wittig reagents

Reported here is the catalytic, acceptorless coupling of alcohols with in situ generated, non-stabilized phosphonium ylides to form olefins as major products. The reaction uses low catalyst loadings and does not require added oxidants. Hydrogenation of the product is minimized and the reaction leads to Z (aliphatic) or E (benzylic) stereospecificity.

A selective Ru-catalyzed semireduction of alkynes to Z olefins under transfer-hydrogenation conditions

By using a readily available, air- and moisture-stable dihydrido-Ru complex, a variety of Z olefins are accessible under transfer-hydrogenation conditions with formic acid as the hydrogen source in excellent yields and Z/E selectivities. A discerning transformation: Z-Configured C=C bonds are stereoselectively formed from alkynes in the presence of a Ru catalyst with formic acid as the sole H2 source at room temperature (see scheme). A variety of functional groups are compatible with this novel procedure. Operational simplicity and the lack of overreduction products are characteristics for this unprecedented process.

METHOD FOR ISOMERIZING ORGANIC COMPOUND

PROBLEM TO BE SOLVED: To provide a method for isomerizing a compound bearing a hydrocarbon group having a carbon-carbon double bond which permits transfer of the carbon-carbon double bond of the compound without using a catalyst or an organic solvent. SOLUTION: The method for isomerizing the compound comprises transferring the position of the carbon-carbon double bond by causing the compound bearing the hydrocarbon group having the carbon-carbon double bond to non-catalytically react in a reaction medium in a high-temperature and high-pressure state. Thus, the isomer having the double bond transferred is obtained in a short time in one step by pressing the compound bearing the hydrocarbon group having the carbon-carbon double bond into high-temperature high-pressure water as a reaction site at a high speed. Neither waste nor wastewater to dispose of is discharged from the manufacturing processes.