19423-77-9Relevant academic research and scientific papers
Solubility in the LaCl3-LnCl3-HCl-H2O (Ln = Pr, Nd) systems at 25°C
Knyazeva,Skiba,Serba
, p. 592 - 595 (2012/07/14)
The solubility in the quaternary water-salt systems LaCl 3-NdCl3-HCl-H2O (1) and LaCl3- PrCl3-HCl-H2O (2) at 25°C was studied in the section of 40 wt % hydrochloric acid, a system with a eutonic discontinuity. The composition at the point of discontinuity for the eutonic solution is the following. In system 1: 4.67 wt % LaCl3 · 7H2O, 0.37 wt % PrCl3 · 7H2O, 37.98 wt % HCl, and 56.98 wt % H2O; in system 2: 4.37 wt % LaCl3 · 7H 2O, 0.93 wt % NdCl3 · 6H2O, 37.88 wt % HCl, and 56.82 wt % H2O.
Synthesis, structure, thermal and luminescent behaviors of lanthanide-Pyridine-3,5-dicarboxylate frameworks series
?yszczek, Renata
, p. 120 - 127 (2011/01/08)
The isostructural series of lanthanide pyridine-3,5-dicarboxylates of the formula [Ln2pdc3(dmf)2]·(dmf) x(H2O)y where Ln are lanthanides from La(III) to Lu(III); pdc2--C5/s
Solubility in the PrCl3-SmCl3-HCl-H2O System at 25°C
Knyazeva,Skiba,Voskoboinikov
, p. 125 - 127 (2009/05/06)
The solubility in the PrCl3-SmCl3-HCl-H2O quaternary water-salt system was studied at 25°C along the 40% hydrochloric acid section (a system with solid solutions and discontinuity). The composition of the discontinuity poi
Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid
Wang, Chun-Guang,Xing, Yong-Heng,Li, Zhang-Peng,Li, Jing,Zeng, Xiao-Qing,Ge, Mao-Fa,Niu, Shu-Yun
, p. 126 - 131 (2009/08/15)
A series of new lanthanide coordination polymers, with the formula [Ln(Suc)0.5(p-BDC)] (Ln = Eu (1), Sm (2), Tb (3), Pr (4), Ho (5); H2Suc = succinic acid; p-H2BDC = 1,4-benzene dicarboxylic acid), have been synthesized un
Synthesis, structure, and antibacterial properties of ternary rare-earth complexes with o-methylbenzoic Acid and 1,10-phenanthroline1
Chen,Wang,Yang,Zhao,Zhang,Wang,Zhao
, p. 541 - 546 (2009/12/02)
Ternary rare-earth complexes with o-methylbenzoic acid (o-MBA) and 1,10-phenanthroline (Phen) Ln2(o-MBA)6(Phen)2 ? nH2O(n = 0, 1) (Ln = La, Pr, Y, Yb) were synthesized and characterized by elemental analysis, IR
Syntheses and characterization of novel lanthanide adamantine-dicarboxylate coordination complexes
Li, Xing,Wei, Dan-Yi,Huang, Shi-Jie,Zheng, Yue-Qing
, p. 95 - 101 (2009/04/14)
Hydrothermal reactions of 1,10-phenanthroline (phen), 1,3-adamantanedicarboxylic acid (H2L) and lanthanide chlorides yielded six compounds: [Ln(L)(HL)(phen)] (Ln=Pr, 1; Nd, 2), [Ln(L)(HL)(phen)(H2O)] (Sm, 3; Eu, 4), [Tb(L)(HL)(phen)(
Phase equilibrium system of RbCl-PrCl3-HCl(12.86 mass %)-H 2O at 298.15 K and standard molar enthalpy of formation of new solid-phase compound
Qiao, Zhanping,Gao, Junlin,Zhuo, Lihong,Zhang, Meili,Zhang, Shuai
, p. 1474 - 1478 (2009/12/04)
The equilibrium solubility of the quaternary system RbCl-PrCl 3-HCl-H2O was determined at 298.15 K and the corresponding equilibrium diagram was constructed in this paper. The quaternary system is complicated with three equilibrium s
Synthesis, structure and properties of [Pr(DMSO)5(H 2O)2](μ-CN)[Co(CN)5]·H2O
Chen, Wen-Tong,Zeng, Xi-Rui,Xu, Ya-Ping,Luo, Qiu-Yan,Chen, Hua-Long
, p. 32 - 36 (2008/09/19)
A new cyano-bridged praseodymiumIII-cobaltIII complex [Pr(DMSO)5(H2O)2](μ-CN)[Co(CN) 5]·H2O, (1), has been synthesized via solution reaction and characterized by X-ray diffraction. The slightly distorted square-antiprism eightfold-coordinated Pr(III) and the approximately oriented octahedrally sixfold-coordinated Co(III) are linked by a cyano-bridge group to form a dinuclear complex. The [Pr(DMSO)5(H2O) 2](μ-CN)[Co(CN)5] species are held together via hydrogen bonds to form a two-dimensional slab. The magnetic properties show that complex 1 exhibits antiferromagnetic interactions. IR and thermogravimetry- differential thermal analyses (TG-DTA) are also presented.
Reassignment of the crystal space group of crystalline Pr[M(CN)6] · 5H2O (M = Cr, Fe, Co)
Zhang, Lin-Ping,Zhou, Xian-ju,Mak, Thomas C.W.,Tanner, Peter A.
, p. 4019 - 4023 (2008/10/09)
Refinement of the X-ray crystal structures of Pr[M(CN)6] · 5H2O (M = Cr, Fe, Co) enables their space group to be reassigned to P63/mmc. Spectral characteristics are reported for M = Cr and the distinction between the penta
Two novel R- and S-malato-bridged coordination polymers by reacting lanthanide chloride and maleic anhydride, 1,10-phenanthroline at hydrothermal condition
Zhang, Li-Ping,Huang, Liang,Qu, Ling-bo,Peng, Hua,Zhao, Yu-Fen
, p. 14 - 17 (2007/10/03)
Two less common lanthanide coordination polymers, [Ln2(fum)(malate)2(phen)2]n ·n1.25H2O (Ln=Eu, 1; Pr, 2. fum=fumarate, phen=1,10-phenanthroline) were synthesized and characterized by IR spectra and X-ray crystallography. Single crystal X-ray diffraction analysis shows that complex 1 is isostructural with complex 2. In the two complexes, we found a pair of enantiomers (R-malate and S-malate) which are obtained by addition reaction between maleate and water and fumarate which result from configurational tranformation of maleate. The two structures consist of coordination polymer chains along the c-axis which are held together solely through hydrogen bonding and π-π stacking. Three-dimension supramolecular structures are formed through the two types of weak interaction. The IR data are also described and compared with those of other similar complexes.
