194285-51-3Relevant articles and documents
Stimuli-Responsive B/N Lewis Pairs Based on the Modulation of B-N Bond Strength
Hou, Qinggao,Liu, Lijie,Mellerup, Soren K.,Wang, Nan,Peng, Tai,Chen, Pangkuan,Wang, Suning
, p. 6467 - 6470 (2018)
A series of robust organoboranes with electronically tunable functionality of B/N Lewis pairs has been achieved. These compounds feature a B/N-containing core in which the interactions between the B and N atoms are modulated as a result of the structural
Hypervalent organoantimony compounds 12-ethynyl-tetrahydrodibenz[c,f][1,5]azastibocines: Highly efficient new transmetallating agent for organic halides
Kakusawa, Naoki,Tobiyasu, Yoshinori,Yasuike, Shuji,Yamaguchi, Kentaro,Seki, Hiroko,Kurita, Jyoji
, p. 2953 - 2968 (2007/10/03)
Extremely efficient and high-speed ethynylation of acyl chlorides, aryl iodides and bromides was demonstrated by palladium-catalyzed cross-coupling reaction of N-t-butyl-Sb-ethynyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azastibocine under mild conditions. Optimization and generalization of the hypervalent antimony-mediated coupling reaction are presented in detail. Single-crystal X-ray analysis of the N-methyl-1,5-azastibocine revealed that the remarkable reactivity enhancement of the azastibocine was derived from elongation of the antimony-ethynyl carbon bond originated from Sb-N intramolecular non-bonding interaction.