194352-08-4Relevant academic research and scientific papers
One-Pot Formation of Carbonates from the Reactions of Carbonyl Compounds with Samarium Diiodide and Methyl Chloroformate
Lu, Ling,Fang, Jim-Min,Lee, Gene-Hsiang,Wang, Yu
, p. 279 - 289 (1997)
Treatment of carbonyl compounds with SmI2 and methyl chloroformate in the presence of molecular sieves provides the cyclic carbonates or biscarbonates of pinacols. This one-pot reaction proceeds rapidly even with aliphatic ketones. The stereoch
