One-Pot Formation of Carbonates from the Reactions of Carbonyl Compounds with Samarium Diiodide and Methyl Chloroformate

DOI: 10.1002/jccs.199700043

Source and publish data:

Journal of the Chinese Chemical Society p. 279 - 289 (1997)

Update date:2022-08-03

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Authors:

Lu, Ling

Fang, Jim-Min

Lee, Gene-Hsiang

Wang, Yu

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Article abstract of DOI:10.1002/jccs.199700043

Treatment of carbonyl compounds with SmI₂ and methyl chloroformate in the presence of molecular sieves provides the cyclic carbonates or biscarbonates of pinacols. This one-pot reaction proceeds rapidly even with aliphatic ketones. The stereoch

Full text of DOI:10.1002/jccs.199700043

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