19437-01-5

Basic information

• Product Name: TRANS-1-PHENYL-4-TERT-BUTYLCYCLOHEXANOL
• Synonyms: TRANS-1-PHENYL-4-TERT-BUTYLCYCLOHEXANOL;4-tert-butyl-1-phenylcyclohexanol
• CAS NO: 19437-01-5
• Molecular Formula: C₁₆H₂₄O
• Molecular Weight: 232.36
• Mol File: 19437-01-5.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: TRANS-1-PHENYL-4-TERT-BUTYLCYCLOHEXANOL(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-1-PHENYL-4-TERT-BUTYLCYCLOHEXANOL(19437-01-5)
• EPA Substance Registry System: TRANS-1-PHENYL-4-TERT-BUTYLCYCLOHEXANOL(19437-01-5)

Safety Data

• Hazardous Substances Data: 19437-01-5(Hazardous Substances Data)

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 100-58-3 phenylmagnesium bromide 
• 591-50-4 iodobenzene 
• 16635-23-7 phenyltriisopropoxytitanium(IV) 

Downstream Products

• 98-53-3 4-tercbutyl-cyclohexanone 
• 103-84-4 Acetanilid 
• 3419-73-6 1-phenyl-4-tert-butylcyclohexene 
• 1625-92-9 4-tert-butylbiphenyl 

Relevant articles and documents

Electrophotochemical Ring-Opening Bromination oftert-Cycloalkanols

An electrophotochemical ring-opening bromination of unstrainedtert-cycloalkanols has been developed. This electrophotochemical method enables the oxidative transformation of cycloalkanols with 5- to 7-membered rings into synthetically useful ω-bromoketones without the use of chemical oxidants or transition-metal catalysts. Alkoxy radical species would be key intermediates in the present transformation, which generate through homolysis of the O-Br bond in hypobromite intermediates under visible light irradiation.

Barbier-type reactions of aryl halides with ketones mediated by Samarium diiodide

Barbier-type reaction of aryl halides with ketones took place on treatment with samarium diiodide in benzene containing 10% hexamethylphosphoric triamide (HMPA). The reaction involves an aryl samarium as an intermediate.