19480-04-7

Upstream product

• 591-49-1 1-methylcyclohex-1-ene 
• 109-49-9 5-Hexen-2-one 
• 201230-82-2 carbon monoxide 
• 67-56-1 methanol 

Downstream Products

• 41368-27-8 7-Cyclohexyl-7-hydroxy-heptan-2-one 
• 80313-88-8 2-Phenylseleno-6-oxo-heptanal 
• 16112-10-0 1-(cyclopent-1-en-1-yl)ethanone 
• 123445-70-5 1,1,6,6-tetrakis(phenylseleno)heptane 
• 112586-64-8 3-hydroxy-1-phenylnonane-1,8-dione 
• 868359-23-3 1-phenylnon-2-ene-1,8-dione 
• 868359-25-5 1-p-tolylnon-2-ene-1,8-dione 
• 868359-24-4 1-(4-methoxyphenyl)non-2-ene-1,8-dione 
• 868359-26-6 1-(4-bromophenyl)non-2-ene-1,8-dione 
• 96304-40-4 (R)-(+)-2-hydroxy-2-methylcyclohexanone 
• 123445-73-8 ((1Z,7E)-2-Methyl-trideca-1,7-dienyl)-benzene 
• 123445-72-7 7-Methyl-7,12-bis-phenylselanyl-octadecane-6,13-diol 
• 123445-71-6 2-Methyl-1-phenyl-2,7-bis-phenylselanyl-tridecane-1,8-diol 
• 67209-77-2 2-methyl-cyclopent-1-enecarboxylic acid 

Relevant academic research and scientific papers

Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols

Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions. Copyright

Carbon monoxide solubility in ionic liquids: Determination, prediction and relevance to hydroformylation

The solubility of carbon monoxide in 37 ionic liquids and in some organic solvents has been determined using high-pressure 13C NMR spectroscopy; a method for predicting the CO solubility is demonstrated, and it was shown that the rate of the hydroformylation of 5-hexen-2-one does not correlate with the CO solubility, as expected from the determined relative solubility of CO compared to H2.

Reactions of Ozone with 1-Methylcyclohexene and Methylenecyclohexane in Air

Reactions of ozone with 1-methylcyclohexene and methylenecyclohexane were studied for the purpose of obtaining the reaction mechanism as a prototype of the reaction of ozone with pinenes.The similarity of the yields of corresponding gaseous products between 1-methylcyclohexene and α-pinene and between methylenecyclohexane and β-pinene indicates the similarity of the reaction mechanisms.