194937-63-8Relevant academic research and scientific papers
Hypervalent iodine oxidation of trimethylsilyl ketene acetals: A convenient route to α-methoxylation of esters and lactones
Moriarty, Robert M.,Rani, Neena,Condeiu, Cristian,Duncan, Michael P.,Prakash, Om
, p. 3273 - 3277 (1997)
Hypervalent iodine oxidation of trimethylsilyl ketene acetals of esters and lactones using iodosobenzene in methanol affords the corresponding α- methoxylated carbonyl compounds in good yields.
Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis
Jia, Yi-Xia,Hillgren, J. Mikael,Watson, Emma L.,Marsden, Stephen P.,Kuendig, E. Peter
supporting information; scheme or table, p. 4040 - 4042 (2009/03/11)
The Pd-catalysed asymmetric intramolecular α-arylation of amide enolates containing heteroatom substituents gives chiral 3-alkoxy or 3-aminooxindoles in high yield and with enantioselectivities up to 97% ee when a new chiral N-heterocyclic carbene ligand is used. The Royal Society of Chemistry.
