Hypervalent iodine oxidation of trimethylsilyl ketene acetals: A convenient route to α-methoxylation of esters and lactones

Article abstract of DOI:10.1080/00397919708004187

Hypervalent iodine oxidation of trimethylsilyl ketene acetals of esters and lactones using iodosobenzene in methanol affords the corresponding α- methoxylated carbonyl compounds in good yields.

Full text of DOI:10.1080/00397919708004187

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Hypervalent Iodine Oxidation
of Trimethylsilyl Ketene
Acetals: A Convenient Route to
α-Methoxylation of Esters and
Lactones
Robert M. Moriarty a , Neena Rani a , Cristian
Condeiu a , Michael P. Duncan a & Om Prakash a
a Department of Chemistry , University of Illinois ,
Chicago, IL., 60607, USA
Published online: 22 Aug 2006.
To cite this article: Robert M. Moriarty , Neena Rani , Cristian Condeiu , Michael P.
Duncan & Om Prakash (1997) Hypervalent Iodine Oxidation of Trimethylsilyl Ketene
Acetals: A Convenient Route to α-Methoxylation of Esters and Lactones, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 27:18, 3273-3277, DOI: 10.1080/00397919708004187
To link to this article: http://dx.doi.org/10.1080/00397919708004187
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